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Beilstein J. Org. Chem. 2016, 12, 1573–1576, doi:10.3762/bjoc.12.152
Graphical Abstract
Figure 1: Selected M→B coordination modes 1–5 [6-10] and Hofmann’s Rucaphos complex 6 [11].
Scheme 1: Synthesis of diphosphinoborane CyDPBPh and complex 9.
Figure 2: Thermal ellipsoid plots of complex 9 at the 50% probability level. H atoms and one molecule of hexa...